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Abstract Spectral lines of ammonia, NH 3 , are useful probes of the physical conditions in dense molecular cloud cores. In addition to advantages in spectroscopy, ammonia has also been suggested to be resistant to freezing onto grain surfaces, which should make it a superior tool for studying the interior parts of cold, dense cores. Here we present high-resolution NH 3 observations with the Very Large Array and Green Bank Telescope toward a prestellar core. These observations show an outer region with a fractional NH 3 abundance of X (NH 3 ) = (1.975 ± 0.005) × 10 −8 (±10% systematic), but it also reveals that, after all, the X (NH 3 ) starts to decrease above a H 2 column density of ≈2.6 × 10 22 cm −2 . We derive a density model for the core and find that the break point in the fractional abundance occurs at the density n (H 2 ) ∼ 2 × 10 5 cm −3 , and beyond this point the fractional abundance decreases with increasing density, following the power law n −1.1 . This power-law behavior is well reproduced by chemical models where adsorption onto grains dominates the removal of ammonia and related species from the gas at high densities. We suggest that the break-point density changes from core to core depending on the temperature and the grain properties, but that the depletion power law is anyway likely to be close to n −1 owing to the dominance of accretion in the central parts of starless cores. 

Abstract Prestellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures (<10 K) allow the formation of thick icy dust mantles, which will be partially preserved in future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in prestellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH 3 and, in particular, its deuterated isotopologues appear to maintain high abundances where CO molecules are mainly in the solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH 2 D freeze-out toward the L1544 prestellar core, suggestive of the presence of a “complete depletion zone” within a ≃1800 au radius, in agreement with astrochemical prestellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH 2 D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing out already at ≃7000 au. Radiative transfer effects within the prestellar core cause the NH 2 D(1 11 − 1 01 ) emission to appear centrally concentrated, with a flattened distribution within the central ≃3000 au, unlike the 1.3 mm dust continuum emission, which shows a clear peak within the central ≃1800 au. This prevented NH 2 D freeze-out from being detected in previous observations, where the central 1000 au cannot be spatially resolved.